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Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process

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Bibliographic Details
Main Authors: Ambrová, Marta, Korenko, Michal, Szatmáry, Lórant
Format: Book
Language:English
Published: Springer 2023
Subjects:
Current Efficiency
Aluminum Electrolysis Process
Online Access:https://link.springer.com/article/10.1007/s11663-023-02855-9
https://dlib.phenikaa-uni.edu.vn/handle/PNK/9500
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spelling oai:localhost:PNK-95002023-10-06T08:48:23Z Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process Ambrová, Marta Korenko, Michal Szatmáry, Lórant Current Efficiency Aluminum Electrolysis Process CC-BY The influence of sulfur species on the current efficiency and carbon consumption in the aluminum electrolysis was investigated. Prebaked and graphite anodes with varying levels of sulfur were used. It was found that increasing the sulfur content in the anodes decreases the current efficiency and increases the carbon consumption of both types of anodes. The current efficiency decreased by 1.3 pct and the carbon consumption rose by 6.1 pct per 1 wt pct S in the prebaked anodes. The addition of sodium sulfate to the electrolyte during electrolysis with graphite anodes led to a decrease in current efficiency from 0.9 to 1.0 pct per 1 wt pct S, and to an increase in carbon consumption from 3.1 to 7.0 pct per 1 wt pct S. Electrolyte analysis showed the presence of sulfates, sulfides and polysulfides. Some link between sulfur content in the anodes and sulfur content in the electrolyte and outgoing gases was found. A comparison of the polarized and non-polarized conditions showed that the electrolysis increases the sulfur depletion from the cell and promotes the formation of soluble sulfides. 2023-10-06T08:48:23Z 2023-10-06T08:48:23Z 2023 Book https://link.springer.com/article/10.1007/s11663-023-02855-9 https://dlib.phenikaa-uni.edu.vn/handle/PNK/9500 en application/pdf Springer
institution Digital Phenikaa
collection Digital Phenikaa
language English
topic Current Efficiency
Aluminum Electrolysis Process
spellingShingle Current Efficiency
Aluminum Electrolysis Process
Ambrová, Marta
Korenko, Michal
Szatmáry, Lórant
Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
description CC-BY
format Book
author Ambrová, Marta
Korenko, Michal
Szatmáry, Lórant
author_facet Ambrová, Marta
Korenko, Michal
Szatmáry, Lórant
author_sort Ambrová, Marta
title Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
title_short Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
title_full Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
title_fullStr Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
title_full_unstemmed Influence of the Sulfur Species on the Current Efficiency and Carbon Consumption in the Aluminum Electrolysis Process
title_sort influence of the sulfur species on the current efficiency and carbon consumption in the aluminum electrolysis process
publisher Springer
publishDate 2023
url https://link.springer.com/article/10.1007/s11663-023-02855-9
https://dlib.phenikaa-uni.edu.vn/handle/PNK/9500
_version_ 1779307187253805056
score 8.891145

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