Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys
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oai:localhost:PNK-94622023-10-05T01:57:22Z Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys Pajor, Krzysztof Gondek, Łukasz Tyrała, Dorota XRD DTA Cc-BY Zr-based bulk metallic glasses (BMGs) are characterized by excellent glass-forming ability, combined with superior mechanical properties. However, oxygen impurities degrade both these aspects as oxides serve as heterogeneous nucleation sites during solidification. Rare-earth elements (REEs) are known to be good oxygen scavengers, binding oxygen to less harmful forms. The most stable rare-earth oxide (REO) is M2O3, which occurs in three polymorphic forms, depending on the radius of metal cation: cubic, hexagonal, and monoclinic. Here, we show the effect of Sc, Y, Lu, Nd, and Gd additions in relation to the oxygen content on the glass-forming ability of the Zr52.5Cu17.9Ni14.6Al10Ti5 alloy. Microscopic observations (SEM) supported by chemical analysis (EDS, WDS), structure identification (XRD), and thermal analysis (DTA) were carried out. 2023-10-05T01:57:22Z 2023-10-05T01:57:22Z 2023 Book https://link.springer.com/article/10.1007/s11661-023-07176-9 https://dlib.phenikaa-uni.edu.vn/handle/PNK/9462 en application/pdf Springer |
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XRD DTA |
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XRD DTA Pajor, Krzysztof Gondek, Łukasz Tyrała, Dorota Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
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Cc-BY |
format |
Book |
author |
Pajor, Krzysztof Gondek, Łukasz Tyrała, Dorota |
author_facet |
Pajor, Krzysztof Gondek, Łukasz Tyrała, Dorota |
author_sort |
Pajor, Krzysztof |
title |
Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
title_short |
Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
title_full |
Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
title_fullStr |
Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
title_full_unstemmed |
Advancing Bulk Metallic Glass Formation: Utilizing Rare-Earth Elements in Zr-Based Alloys |
title_sort |
advancing bulk metallic glass formation: utilizing rare-earth elements in zr-based alloys |
publisher |
Springer |
publishDate |
2023 |
url |
https://link.springer.com/article/10.1007/s11661-023-07176-9 https://dlib.phenikaa-uni.edu.vn/handle/PNK/9462 |
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1779307184013705216 |
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8.891787 |