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Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal

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Main Authors: 000377Vázquez, M. Vázquez, Blanco, M. J. Díaz, Figueroa, R. A. Parra
Format: Book
Language:English
Published: Springer 2023
Subjects:
thermal oxidation
oxidative conditions
Online Access:https://link.springer.com/article/10.1007/s11085-023-10169-z
https://dlib.phenikaa-uni.edu.vn/handle/PNK/9071
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spelling oai:localhost:PNK-90712023-09-18T04:53:47Z Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal 000377Vázquez, M. Vázquez Blanco, M. J. Díaz Figueroa, R. A. Parra thermal oxidation oxidative conditions CC-BY The kinetics of the thermal oxidation of white metal and Cu2S have been studied by thermogravimetric analysis (TG), which was carried out under atmospheric oxidative conditions (O2 100%) with heating rates of 5, 10, 15 and 20 °C min−1. Each experiment was performed three times, the indicated values being the average of the three experiments. The experimental data were evaluated using isoconversional models based on the Arrhenius equation. The models are constructed using first-order mechanisms in the reactions and therefore, since most of them present adequate regression coefficients, it can be verified that order 1 is the most predominant order among the reactions found. In addition, the Kissinger–Akahira–Sunose model, which has the highest regression coefficient, is considered to be the most optimal. Similar behavior was recorded between Cu2S and white metal, as well as a similar regular increase in the apparent activation energy (Ea) of 10–30 kJ mol−1 for both materials. 2023-09-18T04:53:47Z 2023-09-18T04:53:47Z 2023 Book https://link.springer.com/article/10.1007/s11085-023-10169-z https://dlib.phenikaa-uni.edu.vn/handle/PNK/9071 en application/pdf Springer
institution Digital Phenikaa
collection Digital Phenikaa
language English
topic thermal oxidation
oxidative conditions
spellingShingle thermal oxidation
oxidative conditions
000377Vázquez, M. Vázquez
Blanco, M. J. Díaz
Figueroa, R. A. Parra
Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
description CC-BY
format Book
author 000377Vázquez, M. Vázquez
Blanco, M. J. Díaz
Figueroa, R. A. Parra
author_facet 000377Vázquez, M. Vázquez
Blanco, M. J. Díaz
Figueroa, R. A. Parra
author_sort 000377Vázquez, M. Vázquez
title Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
title_short Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
title_full Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
title_fullStr Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
title_full_unstemmed Thermal Oxidative Degradation of Pure Cu2S and Industrial White Metal
title_sort thermal oxidative degradation of pure cu2s and industrial white metal
publisher Springer
publishDate 2023
url https://link.springer.com/article/10.1007/s11085-023-10169-z
https://dlib.phenikaa-uni.edu.vn/handle/PNK/9071
_version_ 1779307152316301312
score 8.891053

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