Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity
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2023
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oai:localhost:PNK-89372023-08-25T02:36:57Z Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity Yang, Pengfei Xu, Linlin Trogadas, Panagiotis PEMs cucurbit[n]urils (CB[n] Cc-BY Enhancing the proton conductivity of proton exchange membranes (PEMs) is essential to expand the applications of proton exchange membrane fuel cells (PEMFCs). Inspired by the proton conduction mechanism of bacteriorhodopsin, cucurbit[n]urils (CB[n], where n is the number of glycoluril units, n = 6, 7, or 8) are introduced into sulfonated poly(ether ether ketone) (SPEEK) matrix to fabricate hybrid PEMs, employing a nature-inspired chemical engineering (NICE) methodology. The carbonyl groups of CB[n] act as proton-conducting sites, while the host–guest interaction between CB[n] and water molecules offers extra proton-conducting pathways. Additionally, the molecular size of CB[n] aids in their dispersion within the SPEEK matrix, effectively bridging the unconnected proton-conducting sulfonic group domains within the SPEEK membrane. 2023-08-25T02:36:57Z 2023-08-25T02:36:57Z 2023 Book https://link.springer.com/article/10.1007/s12274-023-6009-z https://dlib.phenikaa-uni.edu.vn/handle/PNK/8937 en application/pdf Springer |
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Digital Phenikaa |
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Digital Phenikaa |
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PEMs cucurbit[n]urils (CB[n] |
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PEMs cucurbit[n]urils (CB[n] Yang, Pengfei Xu, Linlin Trogadas, Panagiotis Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
description |
Cc-BY |
format |
Book |
author |
Yang, Pengfei Xu, Linlin Trogadas, Panagiotis |
author_facet |
Yang, Pengfei Xu, Linlin Trogadas, Panagiotis |
author_sort |
Yang, Pengfei |
title |
Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
title_short |
Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
title_full |
Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
title_fullStr |
Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
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Bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
title_sort |
bioinspired supramolecular macrocycle hybrid membranes with enhanced proton conductivity |
publisher |
Springer |
publishDate |
2023 |
url |
https://link.springer.com/article/10.1007/s12274-023-6009-z https://dlib.phenikaa-uni.edu.vn/handle/PNK/8937 |
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1775230273358659584 |
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8.891145 |