Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks
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Ngôn ngữ: | English |
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Springer
2023
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Truy cập trực tuyến: | https://link.springer.com/article/10.1007/s10904-023-02653-5 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8183 |
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oai:localhost:PNK-81832023-04-21T01:44:29Z Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks Yuel W., Abraha Francois J. F., Jacobs Alice, Brink de novo SALE CC BY Direct mixing (de novo) and Solvent Assisted Ligand Exchange (SALE) are the main methods used for the synthesis of Mixed-Linker Zeolitic Imidazolate Frameworks (ML-ZIFs). ML-ZIFs with combined –NO2 and –Br/–Cl functionalities were prepared via both synthetic routes. Thereafter the CO2 uptake of the ML-ZIFs were compared, as well as their abilities to fixate CO2 with epoxide substrates. The de novo synthesis resulted in ML-ZIFs with SOD topologies, 60: 40 (–NO2: –Br/–Cl) functionality ratios, higher porosities, better thermal stability and higher CO2 uptake than equivalent SALE products. 2023-04-21T01:44:29Z 2023-04-21T01:44:29Z 2023 Book https://link.springer.com/article/10.1007/s10904-023-02653-5 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8183 en application/pdf Springer |
institution |
Digital Phenikaa |
collection |
Digital Phenikaa |
language |
English |
topic |
de novo SALE |
spellingShingle |
de novo SALE Yuel W., Abraha Francois J. F., Jacobs Alice, Brink Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
description |
CC BY |
format |
Book |
author |
Yuel W., Abraha Francois J. F., Jacobs Alice, Brink |
author_facet |
Yuel W., Abraha Francois J. F., Jacobs Alice, Brink |
author_sort |
Yuel W., Abraha |
title |
Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
title_short |
Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
title_full |
Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
title_fullStr |
Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
title_full_unstemmed |
Effect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworks |
title_sort |
effect of solvent assisted linker exchange (sale) and de novo synthetic routes on co2 uptake and fixation by mixed-linker zeolitic imidazolate frameworks |
publisher |
Springer |
publishDate |
2023 |
url |
https://link.springer.com/article/10.1007/s10904-023-02653-5 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8183 |
_version_ |
1763815058145542144 |
score |
8.891145 |