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Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation

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Bibliographic Details
Main Authors: Carola, Haslinger, Anna, Zahoranová, Stefan, Baudis
Format: Book
Language:English
Published: Springer 2023
Subjects:
EtOx
POx)
Online Access:https://link.springer.com/article/10.1007/s00706-022-03013-
https://dlib.phenikaa-uni.edu.vn/handle/PNK/8170
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spelling oai:localhost:PNK-81702023-04-20T08:58:38Z Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation Carola, Haslinger Anna, Zahoranová Stefan, Baudis EtOx POx) CC BY Herein, we present a new route to synthesize poly(2-oxazoline)s (POx) with coumarin moieties as pendant groups that can be crosslinked by irradiation to form hydrogels. The synthesis of a novel coumarin-containing 2-oxazoline monomer, 2-[(4-methyl-7-coumarinyloxy)methyl]oxazoline is described in four steps and further its subsequent homo- and copolymerization with 2-ethyl-2-oxazoline (EtOx) via cationic ring-opening polymerization (CROP). The received polymers with different coumarin content (8, 4 and 2 mol%) were compared with a known copolymer synthesized via postpolymerization modification of partially hydrolyzed poly(2-ethyl-2-oxazoline) (PEtOx) with a coumarin derivative. The thermoresponsive behavior of the POx in aqueous solutions was investigated, showing a clear difference in the cloud point temperature (Tcp) between the polymers synthesized via different strategies. 2023-04-20T08:58:38Z 2023-04-20T08:58:38Z 2023 Book https://link.springer.com/article/10.1007/s00706-022-03013- https://dlib.phenikaa-uni.edu.vn/handle/PNK/8170 en application/pdf Springer
institution Digital Phenikaa
collection Digital Phenikaa
language English
topic EtOx
POx)
spellingShingle EtOx
POx)
Carola, Haslinger
Anna, Zahoranová
Stefan, Baudis
Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
description CC BY
format Book
author Carola, Haslinger
Anna, Zahoranová
Stefan, Baudis
author_facet Carola, Haslinger
Anna, Zahoranová
Stefan, Baudis
author_sort Carola, Haslinger
title Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
title_short Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
title_full Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
title_fullStr Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
title_full_unstemmed Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
title_sort synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
publisher Springer
publishDate 2023
url https://link.springer.com/article/10.1007/s00706-022-03013-
https://dlib.phenikaa-uni.edu.vn/handle/PNK/8170
_version_ 1763724456121860096
score 8.893527

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