Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current
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2023
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oai:localhost:PNK-81452023-04-20T07:01:27Z Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current Kazuaki, Oda Yoshiyuki, Kuroda Shigenori, Mitsushima Charge–Discharging Behavior Alkaline Water Electrolysis CC BY In the bipolar-type alkaline water electrolysis powered by renewable energy, electrocatalysts are degraded by repeated potential change associated with the generation of reverse current. If an electrode has large discharge capacity, the opposite electrode on the same bipolar plate is degraded by the reverse current. In this study, discharge capacity of various transition metal-based electrocatalysts was investigated to clarify the determining factors of electrocatalysts on the reverse current and durability. The discharge capacities from 1.5 to 0.5 V vs. RHE (Qdc,0.5) of electrocatalysts are proportional to the surface area in most cases. The proportionality coefficient, corresponding to the specific capacity, is 1.0 C·m–2 for Co3O4 and 2.3 C·m–2 for manganese-based electrocatalysts. 2023-04-20T07:01:27Z 2023-04-20T07:01:27Z 2023 Book https://link.springer.com/article/10.1007/s12678-023-00815-0 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8145 en application/pdf Springer |
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Charge–Discharging Behavior Alkaline Water Electrolysis |
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Charge–Discharging Behavior Alkaline Water Electrolysis Kazuaki, Oda Yoshiyuki, Kuroda Shigenori, Mitsushima Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
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CC BY |
format |
Book |
author |
Kazuaki, Oda Yoshiyuki, Kuroda Shigenori, Mitsushima |
author_facet |
Kazuaki, Oda Yoshiyuki, Kuroda Shigenori, Mitsushima |
author_sort |
Kazuaki, Oda |
title |
Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
title_short |
Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
title_full |
Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
title_fullStr |
Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
title_full_unstemmed |
Investigation of Charge–Discharging Behavior of Metal Oxide–Based Anode Electrocatalysts for Alkaline Water Electrolysis to Suppress Degradation due to Reverse Current |
title_sort |
investigation of charge–discharging behavior of metal oxide–based anode electrocatalysts for alkaline water electrolysis to suppress degradation due to reverse current |
publisher |
Springer |
publishDate |
2023 |
url |
https://link.springer.com/article/10.1007/s12678-023-00815-0 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8145 |
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1763724454325649408 |
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8.891053 |