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Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics

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Bibliographic Details
Main Authors: Marco, Sigl, Thomas, Rath, Bettina, Schlemmer
Format: Book
Language:English
Published: Springer 2023
Subjects:
PFQ10
Online Access:https://link.springer.com/article/10.1007/s00706-022-03030-7
https://dlib.phenikaa-uni.edu.vn/handle/PNK/8121
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spelling oai:localhost:PNK-81212023-04-20T03:00:57Z Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics Marco, Sigl Thomas, Rath Bettina, Schlemmer PFQ10 CC BY Quinoxaline has recently gained interest as monomer in conjugated copolymers because of its easy synthetic accessibility and successful use in highly efficient organic solar cells. In this contribution, we introduce a quinoxaline–fluorene-co-polymer, PFQ10, synthesized by copolymerization of 5,8-dibromo-6,7-difluoro-2-[(2-hexyldecyl)oxy]quinoxaline and 9,9-dioctyl-9H-9-fluorene-2,7-bis(boronic acid pinacol ester) using the Suzuki–Miyaura reaction. By optimization of the reaction conditions, polymers with molecular weights up to 17.2 kDa and a low dispersity of 1.3 were obtained. PFQ10 showed blue photoluminescence with an emission maximum at 459 nm and a relative fluorescence quantum yield of 0.37. As proof of principle, PFQ10 was employed in organic light-emitting diodes and showed a blue–green electroluminescence. 2023-04-20T03:00:57Z 2023-04-20T03:00:57Z 2023 Book https://link.springer.com/article/10.1007/s00706-022-03030-7 https://dlib.phenikaa-uni.edu.vn/handle/PNK/8121 en application/pdf Springer
institution Digital Phenikaa
collection Digital Phenikaa
language English
topic PFQ10
spellingShingle PFQ10
Marco, Sigl
Thomas, Rath
Bettina, Schlemmer
Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
description CC BY
format Book
author Marco, Sigl
Thomas, Rath
Bettina, Schlemmer
author_facet Marco, Sigl
Thomas, Rath
Bettina, Schlemmer
author_sort Marco, Sigl
title Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
title_short Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
title_full Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
title_fullStr Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
title_full_unstemmed Synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
title_sort synthesis of a fluorene and quinoxaline-based co-polymer for organic electronics
publisher Springer
publishDate 2023
url https://link.springer.com/article/10.1007/s00706-022-03030-7
https://dlib.phenikaa-uni.edu.vn/handle/PNK/8121
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score 8.881002

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