Synthesis, structural and optical properties of ZnS/ZnO heterostructure-alloy hexagonal micropyramids

Heterostructure alloys with controlled structure and composition are essential for future electronics and optoelectronics. While heterostructure formation creates sharp electronic junction, alloying allows bandgap tunability. Herein, ZnS/ZnO heterostructure-alloy hexagonal micropyramids are grown on...

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Bibliographic Details
Main Authors: D.Q.Trung, M.T.Tran, N.Tu
Format: Bài trích
Language:English
Published: Elsevier 2022
Subjects:
Online Access:https://www.sciencedirect.com/science/article/abs/pii/S0925346722001112?via%3Dihub
https://dlib.phenikaa-uni.edu.vn/handle/PNK/5872
https://doi.org/10.1016/j.optmat.2022.112077
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Summary:Heterostructure alloys with controlled structure and composition are essential for future electronics and optoelectronics. While heterostructure formation creates sharp electronic junction, alloying allows bandgap tunability. Herein, ZnS/ZnO heterostructure-alloy hexagonal micropyramids are grown on Si/SiO2 wafers for the first time by facile thermal evaporation of ZnS powder. It is found that the pyramids with a based size of few micrometers are grown along different crystallographic directions and neighbored by ZnS microrods. XRD and XPS spectra showed that ZnS, ZnO, and ZnSO wurtzite phases coexist in the as-received samples