Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance
The present work reports efficient electrochemical nanosensors for the sensitive monitoring of 4-nitrophenol (4-NP) in tomato samples using various biosynthesized silver nanoparticles (bio-AgNPs). Three different bio-AgNP types were synthesized using natural plant extracts, including green tea (GT)...
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Royal Society of Chemistry
2022
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Truy cập trực tuyến: | https://pubs.rsc.org/en/content/articlelanding/2022/RA/D1RA09202B https://dlib.phenikaa-uni.edu.vn/handle/PNK/5734 https://doi.org/10.1039/D1RA09202B |
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oai:localhost:PNK-57342022-08-17T05:54:52Z Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance Nguyen, Le Nhat Trang Dao, Thi Nguyet Nga Van, Tuan Hoang Xuan, Dinh Ngo Pham, Tuyet Nhung Anh,Tuan Le Bio-AgNPs-based Bio-AgNPs-based The present work reports efficient electrochemical nanosensors for the sensitive monitoring of 4-nitrophenol (4-NP) in tomato samples using various biosynthesized silver nanoparticles (bio-AgNPs). Three different bio-AgNP types were synthesized using natural plant extracts, including green tea (GT) leaf, grapefruit peel (GP), and mangosteen peel (MP), aiming to investigate their effects on the formation of bio-AgNPs, as well as the analytical performance of 4-NP. Based on the obtained results, it was found that the phytochemical content in various plant extracts directly influenced the physicochemical parameters of the created bio-AgNPs, such as particle size, crystallinity, and distribution. More importantly, these parameters have decisive effects on the electrocatalytic activity, conductivity, and electrochemical sensing performance of electrodes modified with them for 4-NP detection. Among the three bio-AgNPs evaluated, the GT-AgNPs (using green tea leaf extract) with uniform shape, small size without aggregation, and high crystallinity showed the best analytical performance for 4-NP determination. The electrode-modified GT-AgNPs exhibited a good 4-NP analytical performance with an electrochemical sensitivity of 1.25 μA μM−1 cm−2 and a detection limit of 0.43 μM in the detection range from 0.5 to 50 μM. The practical applicability of the sensor was also studied in tomato samples, promising satisfactory results toward 4-NP detection in other real samples 2022-05-05T07:26:14Z 2022-05-05T07:26:14Z 2022 Bài trích https://pubs.rsc.org/en/content/articlelanding/2022/RA/D1RA09202B https://dlib.phenikaa-uni.edu.vn/handle/PNK/5734 https://doi.org/10.1039/D1RA09202B en Royal Society of Chemistry |
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Digital Phenikaa |
collection |
Digital Phenikaa |
language |
English |
topic |
Bio-AgNPs-based Bio-AgNPs-based |
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Bio-AgNPs-based Bio-AgNPs-based Nguyen, Le Nhat Trang Dao, Thi Nguyet Nga Van, Tuan Hoang Xuan, Dinh Ngo Pham, Tuyet Nhung Anh,Tuan Le Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
description |
The present work reports efficient electrochemical nanosensors for the sensitive monitoring of 4-nitrophenol (4-NP) in tomato samples using various biosynthesized silver nanoparticles (bio-AgNPs). Three different bio-AgNP types were synthesized using natural plant extracts, including green tea (GT) leaf, grapefruit peel (GP), and mangosteen peel (MP), aiming to investigate their effects on the formation of bio-AgNPs, as well as the analytical performance of 4-NP. Based on the obtained results, it was found that the phytochemical content in various plant extracts directly influenced the physicochemical parameters of the created bio-AgNPs, such as particle size, crystallinity, and distribution. More importantly, these parameters have decisive effects on the electrocatalytic activity, conductivity, and electrochemical sensing performance of electrodes modified with them for 4-NP detection. Among the three bio-AgNPs evaluated, the GT-AgNPs (using green tea leaf extract) with uniform shape, small size without aggregation, and high crystallinity showed the best analytical performance for 4-NP determination. The electrode-modified GT-AgNPs exhibited a good 4-NP analytical performance with an electrochemical sensitivity of 1.25 μA μM−1 cm−2 and a detection limit of 0.43 μM in the detection range from 0.5 to 50 μM. The practical applicability of the sensor was also studied in tomato samples, promising satisfactory results toward 4-NP detection in other real samples |
format |
Bài trích |
author |
Nguyen, Le Nhat Trang Dao, Thi Nguyet Nga Van, Tuan Hoang Xuan, Dinh Ngo Pham, Tuyet Nhung Anh,Tuan Le |
author_facet |
Nguyen, Le Nhat Trang Dao, Thi Nguyet Nga Van, Tuan Hoang Xuan, Dinh Ngo Pham, Tuyet Nhung Anh,Tuan Le |
author_sort |
Nguyen, Le Nhat Trang |
title |
Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
title_short |
Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
title_full |
Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
title_fullStr |
Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
title_full_unstemmed |
Bio-AgNPs-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
title_sort |
bio-agnps-based electrochemical nanosensors for the sensitive determination of 4-nitrophenol in tomato samples: the roles of natural plant extracts in physicochemical parameters and sensing performance |
publisher |
Royal Society of Chemistry |
publishDate |
2022 |
url |
https://pubs.rsc.org/en/content/articlelanding/2022/RA/D1RA09202B https://dlib.phenikaa-uni.edu.vn/handle/PNK/5734 https://doi.org/10.1039/D1RA09202B |
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1751856313589039104 |
score |
8.8926115 |