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High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition

Poly(3,4-ethylenedioxythiophene) (PEDOT) is a transparent conductive polymer widely used in flexible photonic and optoelectronic devices because of its excellent electrical and optical properties. However, its current range of applications is limited by its poor stability under high humidity and sol...

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Main Authors:	Amélie, Schultheiss, Abderrahime, Sekkatb, Viet,Huong Nguyen
Format:	Bài trích
Language:	English
Published:	Elsevier 2022
Subjects:	Poly(34-ethylenedioxythiophene) Pedot
Online Access:	https://www.sciencedirect.com/science/article/abs/pii/S0379677921003015?via%3Dihub https://dlib.phenikaa-uni.edu.vn/handle/PNK/5727 https://doi.org/10.1016/j.synthmet.2021.116995
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spelling	oai:localhost:PNK-57272022-08-17T05:54:50Z High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition Amélie, Schultheiss Abderrahime, Sekkatb Viet,Huong Nguyen Poly(34-ethylenedioxythiophene) Pedot Poly(3,4-ethylenedioxythiophene) (PEDOT) is a transparent conductive polymer widely used in flexible photonic and optoelectronic devices because of its excellent electrical and optical properties. However, its current range of applications is limited by its poor stability under high humidity and solar radiations. Encapsulation is an attractive solution to this problem and the development of a low-temperature and scalable deposition method is highly desirable. In this study, we report the use of spatial atomic layer deposition (SALD) to deposit ultrathin layers of ZnO, TiO2, and Al2O3. These nanolayers maintain the electrical performance of the conductive polymer and its high optical transmittance. The use of SALD ensures low-cost and flexible processing with pinhole-free high-quality coatings at atmospheric pressure and high-throughput. The present study is the first to investigate the effect of various multilayer metal oxide encapsulations on the long-term stability of PEDOT-based transparent conductive materials under solar radiations. We demonstrate finally that bilayer TiO2/Al2O3 and TiO2/ZnO coatings preserve the optoelectronic properties of three different PEDOT-based films, namely PEDOT:OTf (OTf = triflate), PEDOT:Sulf (Sulf = sulfate)and PEDOT:PSS (PSS = PolyStyreneSulfonate) films 2022-05-05T07:26:13Z 2022-05-05T07:26:13Z 2022 Bài trích https://www.sciencedirect.com/science/article/abs/pii/S0379677921003015?via%3Dihub https://dlib.phenikaa-uni.edu.vn/handle/PNK/5727 https://doi.org/10.1016/j.synthmet.2021.116995 en Elsevier
institution	Digital Phenikaa
collection	Digital Phenikaa
language	English
topic	Poly(34-ethylenedioxythiophene) Pedot
spellingShingle	Poly(34-ethylenedioxythiophene) Pedot Amélie, Schultheiss Abderrahime, Sekkatb Viet,Huong Nguyen High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
description	Poly(3,4-ethylenedioxythiophene) (PEDOT) is a transparent conductive polymer widely used in flexible photonic and optoelectronic devices because of its excellent electrical and optical properties. However, its current range of applications is limited by its poor stability under high humidity and solar radiations. Encapsulation is an attractive solution to this problem and the development of a low-temperature and scalable deposition method is highly desirable. In this study, we report the use of spatial atomic layer deposition (SALD) to deposit ultrathin layers of ZnO, TiO2, and Al2O3. These nanolayers maintain the electrical performance of the conductive polymer and its high optical transmittance. The use of SALD ensures low-cost and flexible processing with pinhole-free high-quality coatings at atmospheric pressure and high-throughput. The present study is the first to investigate the effect of various multilayer metal oxide encapsulations on the long-term stability of PEDOT-based transparent conductive materials under solar radiations. We demonstrate finally that bilayer TiO2/Al2O3 and TiO2/ZnO coatings preserve the optoelectronic properties of three different PEDOT-based films, namely PEDOT:OTf (OTf = triflate), PEDOT:Sulf (Sulf = sulfate)and PEDOT:PSS (PSS = PolyStyreneSulfonate) films
format	Bài trích
author	Amélie, Schultheiss Abderrahime, Sekkatb Viet,Huong Nguyen
author_facet	Amélie, Schultheiss Abderrahime, Sekkatb Viet,Huong Nguyen
author_sort	Amélie, Schultheiss
title	High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
title_short	High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
title_full	High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
title_fullStr	High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
title_full_unstemmed	High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
title_sort	high performance encapsulation of transparent conductive polymers by spatial atomic layer deposition
publisher	Elsevier
publishDate	2022
url	https://www.sciencedirect.com/science/article/abs/pii/S0379677921003015?via%3Dihub https://dlib.phenikaa-uni.edu.vn/handle/PNK/5727 https://doi.org/10.1016/j.synthmet.2021.116995
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score	8.881002

High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition

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