Effect of ferric ion [Fe3+] and [Fe2+] on SO2 adsorption ability of γ-Fe2O3 nanoparticles for mass-type gas sensors

The sensing material plays a very important role in determining the sensing properties of a gas sensor. In order to synthesise the sensing material, the precursors have a large effect on the properties of the sensing material. In this study, three types of γ-Fe2O3 nanoparticles were prepared with di...

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Bibliographic Details
Main Authors: Nguyen Thanh Vinh, Tran Van Dang, Bui Thi Hang, Anh-Tuan Le, Nguyen Tri Tuan, Le Khanh Vinh, Nguyen Van Quy
Format: Bài trích
Language:English
Published: Sensors and Actuators A: Physical 2021
Subjects:
QCM
Online Access:https://www.sciencedirect.com/science/article/abs/pii/S0924424721004465?via%3Dihub
https://dlib.phenikaa-uni.edu.vn/handle/PNK/3311
https://doi.org/10.1016/j.sna.2021.112981
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Summary:The sensing material plays a very important role in determining the sensing properties of a gas sensor. In order to synthesise the sensing material, the precursors have a large effect on the properties of the sensing material. In this study, three types of γ-Fe2O3 nanoparticles were prepared with different ferric ion concentrations of [Fe3+] and [Fe2+] as precursors, by a typical facile chemical precipitation process and a following annealing treatment. A mass-type gas sensor was fabricated by using a quartz crystal microbalance (QCM) coated with various γ-Fe2O3 nanoparticles. The morphology, crystallisation, and gas adsorption characteristics of the γ-Fe2O3 nanoparticles were investigated. The effect of ferric ion concentrations of [Fe3+] and [Fe2+] on sensing properties is discussed in detail. Interestingly, the sensor based on γ-Fe2O3 nanoparticles synthesised with ferric ion [Fe3+] showed excellent sensing properties for the detection of SO2 gas, with high sensitivity and repeatability at room temperature. The experimental results clearly demonstrate that the γ-Fe2O3 nanoparticle is an excellent sensing material which may be suitable for practical sensing applications.